{"id":1846,"date":"2018-01-02T17:49:55","date_gmt":"2018-01-03T01:49:55","guid":{"rendered":"http:\/\/labs.wsu.edu\/mccloy\/?page_id=1846"},"modified":"2025-03-19T15:52:14","modified_gmt":"2025-03-19T22:52:14","slug":"understanding-influence-of-thermal-history-and-glass-chemistry-on-kinetics-of-phase-separation-and-crystallization-in-borosilicate-glass-ceramic-waste-forms-for-aqueous-reprocessed-high-level-waste","status":"publish","type":"page","link":"https:\/\/labs.wsu.edu\/mccloy\/understanding-influence-of-thermal-history-and-glass-chemistry-on-kinetics-of-phase-separation-and-crystallization-in-borosilicate-glass-ceramic-waste-forms-for-aqueous-reprocessed-high-level-waste\/","title":{"rendered":"Understanding influence of thermal history and glass chemistry on kinetics of phase separation and crystallization in borosilicate glass-ceramic waste forms for aqueous reprocessed high level waste"},"content":{"rendered":"<br \/>\n<section id=\"builder-section-1422857885723\" class=\"row single \">\n<div style=\"\" class=\"column one \">\n<p><a href=\"http:\/\/labs.wsu.edu\/mccloy\"><img decoding=\"async\" loading=\"lazy\" class=\"alignleft wp-image-541 size-full\" src=\"https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015.jpg\" alt=\"Banner_2015\" width=\"793\" height=\"127\" srcset=\"https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015.jpg 793w, https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015-396x63.jpg 396w, https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015-792x127.jpg 792w\" sizes=\"(max-width: 793px) 100vw, 793px\" \/><\/a><\/p>\n<\/p><\/div>\n<\/section>\n<section id=\"builder-section-1422942361466\" class=\"row single gutter\">\n<div style=\"\" class=\"column one \">\n<p><span style=\"color: black;font-size: medium\"><strong>Publications for Understanding influence of thermal history and glass chemistry on kinetics of phase separation and crystallization in borosilicate glass-ceramic waste forms for aqueous reprocessed high level waste<\/strong><\/span><\/p>\n<ul>\n<li><strong>Malin C. J. Dixon Wilkins<\/strong>, <strong>John McCloy<\/strong>, \u201cAeschynite glass-ceramic composites as flexible wasteform for minor actinide wastes,\u201d <em>MRS Advances<\/em>, 9(7), 426-432 (2024). <a href=\"https:\/\/doi.org\/10.1557\/s43580-024-00775-7\">https:\/\/doi.org\/10.1557\/s43580-024-00775-7<\/a><\/li>\n<li>Strzelecki, A.C., Y. Ren, S. Chong, B.J. Riley, H. Xu, <strong>J.S. McCloy<\/strong>, and X. Guo, &#8220;Structure and thermodynamics of calcium rare earth silicate oxyapatites, Ca<sub>2<\/sub>RE<sub>8<\/sub>(SiO<sub>4<\/sub>)<sub>6<\/sub>O<sub>2<\/sub> (RE\u2009=\u2009Pr, Tb, Ho, Tm),&#8221; <em>Physics and Chemistry of Minerals<\/em>, 49(5), 13 (2022). <a href=\"https:\/\/doi.org\/10.1007\/s00269-022-01187-5\">https:\/\/doi.org\/10.1007\/s00269-022-01187-5<\/a><\/li>\n<li>Saehwa Chong, Brian J. Riley, <strong>Emily T. Nienhuis<\/strong>, Dongjin Lee, <strong>John S. McCloy<\/strong>, \u201cSyntheses and crystal structures of rare-earth oxyapatites Ca<sub>2<\/sub>RE<sub>8<\/sub>(SiO<sub>4<\/sub>)<sub>6<\/sub>O<sub>2<\/sub> (RE = Pr, Tb, Ho, Tm),\u201d <em>Journal of Chemical Crystallography<\/em>, 51(3), 293-300 (2021). <a href=\"https:\/\/doi.org\/10.1007\/s10870-020-00857-y\">https:\/\/doi.org\/10.1007\/s10870-020-00857-y<\/a><\/li>\n<li><strong>Hua Chen<\/strong>, <strong>Jos\u00e9 Marcial<\/strong>, <strong>Mostafa Ahmadzadeh<\/strong>, <strong>Deepak Patil<\/strong>, <strong>John McCloy<\/strong>, \u201cPartitioning of rare earths in multiphase nuclear waste glass-ceramics: implications for original glass structure,\u201d <em>International Journal of Applied Glass Science<\/em>, 11(4), 660-675 (2020). <a href=\"https:\/\/doi.org\/10.1111\/ijag.15726\">https:\/\/doi.org\/10.1111\/ijag.15726<\/a><\/li>\n<li>Strzelecki, Andrew; Kriegsman, Kyle; Estevenon, Paul; Goncharov, Vitaliy; Bai, Jianming; Szenknect, St\u00e9phanie; Mesbah, Adel; Wu, Di; <strong>McCloy, John<\/strong>; Dacheux, Nicolas; Guo, Xiaofeng, \u201cHigh temperature thermodynamics of cerium silicates A-Ce<sub>2<\/sub>Si<sub>2<\/sub>O<sub>7<\/sub> and Ce<sub>4.67<\/sub>(SiO<sub>4<\/sub>)<sub>3<\/sub>O,\u201d <em>ACS Earth and Space Chemistry<\/em>, 4(11):2129-2143 (2020). <a href=\"https:\/\/doi.org\/10.1021\/acsearthspacechem.0c00231\">https:\/\/doi.org\/10.1021\/acsearthspacechem.0c00231<\/a><\/li>\n<li><strong>Hua Chen<\/strong>, Baowei Li, Ming Zhao, Xuefeng Zhang, Yongsheng Du, Yu Shi, <strong>John S. McCloy<\/strong>, \u201cLanthanum modification of crystalline phases and residual glass in augite glass ceramics produced with industrial solid wastes\u201d <em>Journal of Non-crystalline Solids, <\/em>524, 119638 (2019). <a href=\"https:\/\/doi.org\/10.1016\/j.jnoncrysol.2019.119638\">https:\/\/doi.org\/10.1016\/j.jnoncrysol.2019.119638<\/a><\/li>\n<li><strong>J.S. McCloy<\/strong>, B.J. Riley, J. Crum, <strong>J. Marcial<\/strong>, J.T. Reiser, K. Kruska, J.A. Peterson, D.R. Neuville, <strong>D.S. Patil<\/strong>, <strong>M. Saleh<\/strong>, K.E. Barnsley, and J.V. Hanna, \u201cCrystallization Study of Rare Earth and Molybdenum Containing Nuclear Waste Glass Ceramics,\u201d <em>Journal of the American Ceramic Society<\/em>, 102(9), 5149-5163 (2019), <a href=\"https:\/\/doi.org\/10.1111\/jace.16406\">https:\/\/doi.org\/10.1111\/jace.16406<\/a><\/li>\n<li><strong>J. McCloy<\/strong>, J<strong>. Marcial<\/strong>, <strong>D. Patil<\/strong>, <strong>M. Saleh<\/strong>, <strong>M. Ahmadzadeh<\/strong>, <strong>H. Chen<\/strong>, J.V. Crum, B.J. Riley, H. Kamat, A. Br\u00e9hault, A. Goel, K.E. Barnsley, J.V. Hanna, P. Rajbhandari, C.L. Corkhill, R.J. Hand, and N.C. Hyatt, \u201cGlass structure and crystallization in boro-alumino-silicate glasses containing rare earth and transition metal cations: a US-UK collaborative program,\u201d <em>MRS Advances<\/em>, 4(17-18), 1029-1043 (2019). <a href=\"https:\/\/doi.org\/10.1557\/adv.2019.99\">https:\/\/doi.org\/10.1557\/adv.2019.99<\/a><\/li>\n<li><strong>J. McCloy<\/strong>, <strong>J. Marcial<\/strong>, B.J. Riley, J. Neuefeind, J. Crum, <strong>D. Patil<\/strong>, \u201cMethod Development for High Temperature In-Situ Neutron Diffraction Measurements of Glass Crystallization on Cooling from Melt,\u201d <em>MRS Advances<\/em>, 4(17-18), 1009-1019 (2019). <a href=\"http:\/\/dx.doi.org\/10.1557\/adv.2019.46\">http:\/\/dx.doi.org\/10.1557\/adv.2019.46<\/a><\/li>\n<li><strong>D. Patil<\/strong>, M. Konale, M. Gabel, O.K. Neill, J.V. Crum, A. Goel, M.C. Stennett, N.C. Hyatt, and <strong>J.S. McCloy<\/strong>, \u201cImpact of rare earth ion size on the phase evolution of MoO<sub>3<\/sub>-containing aluminoborosilicate glass-ceramics,\u201d <em>Journal of Nuclear Materials<\/em>, 510, 539-550, (2018). <a href=\"https:\/\/doi.org\/10.1016\/j.jnucmat.2018.08.004\">https:\/\/doi.org\/10.1016\/j.jnucmat.2018.08.004<\/a><\/li>\n<li>Antoine Brehault, <strong>Deepak Patil<\/strong>, Randall Youngman, Lynn Thirion, John Mauro, Claire Corkhill, <strong>John McCloy<\/strong>, Ashutosh Goel, \u201cCompositional dependence of solubility\/retention of molybdenum oxides in aluminoborosilicate based model nuclear waste glasses,\u201d\u00a0<i>Journal of Physical Chemistry B<\/i>, 122(5), 1714-1729 (2018),\u00a0<a href=\"http:\/\/dx.doi.org\/10.1021\/acs.jpcb.7b09158\" target=\"_blank\" rel=\"noopener noreferrer\">http:\/\/dx.doi.org\/10.1021\/acs.jpcb.7b09158<\/a><\/li>\n<li><strong>J. McCloy<\/strong> and A. Goel, &#8220;Glass-ceramics for nuclear-waste immobilization,&#8221; <em>MRS Bulletin<\/em>, 42(3), 233-240 (2017). <a href=\"https:\/\/doi.org\/10.1557\/mrs.2017.8\">https:\/\/doi.org\/10.1557\/mrs.2017.8<\/a><\/li>\n<\/ul><\/div>\n<\/section>\n","protected":false},"excerpt":{"rendered":"<p><a href=\"http:\/\/labs.wsu.edu\/mccloy\"><img decoding=\"async\" loading=\"lazy\" class=\"alignleft wp-image-541 size-full\" src=\"https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015.jpg\" alt=\"Banner_2015\" width=\"793\" height=\"127\" srcset=\"https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015.jpg 793w, https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015-396x63.jpg 396w, https:\/\/wpcdn.web.wsu.edu\/wp-labs\/uploads\/sites\/99\/2015\/01\/Banner_2015-792x127.jpg 792w\" sizes=\"(max-width: 793px) 100vw, 793px\" \/><\/a><\/p>\n<p><strong>Publications for Understanding influence of thermal history and glass chemistry on kinetics of phase separation and crystallization in borosilicate glass-ceramic waste forms for aqueous reprocessed high level waste<\/strong><\/p>\n<p><strong>Malin C. J. Dixon Wilkins<\/strong>, <strong>John McCloy<\/strong>, \u201cAeschynite glass-ceramic composites as flexible wasteform for minor actinide wastes,\u201d <em>MRS Advances<\/em>, 9(7), 426-432 (2024). <a href=\"https:\/\/doi.org\/10.1557\/s43580-024-00775-7\">https:\/\/doi.org\/10.1557\/s43580-024-00775-7<\/a><br \/> Strzelecki, A.C., Y. Ren, S. Chong, B.J. Riley, H. Xu, <strong>J.S. McCloy<\/strong>, and X. Guo, &#8220;Structure and thermodynamics of calcium rare earth silicate oxyapatites, Ca2RE8(SiO4)6O2 (RE\u2009=\u2009Pr, Tb, Ho, Tm),&#8221; <em>Physics &#8230; <a href=\"https:\/\/labs.wsu.edu\/mccloy\/understanding-influence-of-thermal-history-and-glass-chemistry-on-kinetics-of-phase-separation-and-crystallization-in-borosilicate-glass-ceramic-waste-forms-for-aqueous-reprocessed-high-level-waste\/\" class=\"more-link\"><span class=\"more-default\">&raquo; More &#8230;<\/span><\/a><\/em><\/p>\n","protected":false},"author":2,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"template-builder.php","meta":{"_wsuwp_accessibility_report":[]},"wsuwp_university_location":[334],"wsuwp_university_org":[409],"_links":{"self":[{"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/pages\/1846"}],"collection":[{"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/comments?post=1846"}],"version-history":[{"count":14,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/pages\/1846\/revisions"}],"predecessor-version":[{"id":2941,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/pages\/1846\/revisions\/2941"}],"wp:attachment":[{"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/media?parent=1846"}],"wp:term":[{"taxonomy":"wsuwp_university_location","embeddable":true,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/wsuwp_university_location?post=1846"},{"taxonomy":"wsuwp_university_org","embeddable":true,"href":"https:\/\/labs.wsu.edu\/mccloy\/wp-json\/wp\/v2\/wsuwp_university_org?post=1846"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}