Publications for Studies and Analyses of Compositional Dependence of Glass Corrosion Associated with Nepheline Formation

• E. T. Nienhuis, M. Tuheen, J. Du, and J.S. McCloy, “In situ pair distribution function analysis of crystallizing Fe-silicate melts,” Journal of Materials Science, 56, 5637–5657 (2021). https://doi.org/10.1007/s10853-020-05643-x
• Nienhuis, E.T., N.J. Smith-Gray, G.N. Cocking, J. Marcial, Y. Zhang, M. Ahmadzadeh, A. Goel, and J.S. McCloy, “A comparative study on the effect of Zr, Sn, and Ti on the crystallization behavior of nepheline glass,” Journal of Non-Crystalline Solids, 569, 120970 (2021). https://doi.org/10.1016/j.jnoncrysol.2021.120970
• Emily Nienhuis, José Marcial, Thibaut Robine, Charles Le Losq, Daniel R. Neuville, Martin C. Stennett, Neil C. Hyatt, John S. McCloy, “Effect of Ti⁴⁺ on the Structure of Nepheline (NaAlSiO₄) Glass,” Geochimica Cosmochimica Acta, 290, 333-351 (2020), https://doi.org/10.1016/j.gca.2020.09.015
• M. Ahmadzadeh, A. Scrimshire, L. Mottram, M. Stennett, N. Hyatt, P. A. Bingham, J. S. McCloy, “Structure of NaFeSiO₄, NaFeSi₂O₆, and NaFeSi₃O₈ glasses and glass-ceramics,” American Mineralogist, 105:1375-1384 https://doi.org/10.2138/am-2020-7285
• I. Sargin, C. E. Lonergan, J. D. Vienna, J. S. McCloy, and S. P. Beckman, “A Data‐Driven Approach for Predicting Nepheline Crystallization in High‐Level Waste Glasses,” Journal of the American Ceramic Society, 103(9), 4913-4924 (2020). https://doi.org/10.1111/jace.17122
• J. Marcial, O.K. Neill, M. Newville, J.V. Crum, and J. McCloy, “Effect of cooling profile on crystalline phases, oxidation state, and chemical partitioning of complex glasses,” MRS Advances, 5(11), 569-579 (2020). https://doi.org/10.1557/adv.2020.89
• Ashutosh Goel, John S. McCloy, Richard Pokorny, Albert A. Kruger, “Challenges with Vitrification of Hanford High-Level Waste (HLW) to Borosilicate Glass – An overview” Journal of Non-Crystalline Solids: X 4, 100033 (2019). https://doi.org/10.1016/j.nocx.2019.100033
• Jose Marcial, Muad Saleh, Deborah Watson, Steve W. Martin, Charles L. Crawford, John McCloy, “Boron-speciation and Aluminosilicate Crystallization in Alkali Boroaluminosilicate Glasses along the NaAl_1-xB_xSiO₄ and LiAl_1-xB_xSiO₄ joins,” Journal of Noncrystalline Solids, 506, 58-67 (2019). https://doi.org/10.1016/j.jnoncrysol.2019.01.001
• J. Marcial and J. McCloy, “Role of short range order on crystallization of tectosilicate glasses: A diffraction study,” Journal of Non-Crystalline Solids, 505, 131-143 (2019). https://doi.org/10.1016/j.jnoncrysol.2018.10.050
• A. Deshkar, M. Ahmadzadeh, A. Scrimshire, E. Han, P.A. Bingham, D. Guillen, J. McCloy, A. Goel, “Dependence of crystallization on composition and heating atmosphere in iron-containing model nuclear waste glasses,” Journal of the American Ceramic Society, 102(3), 1101-1121 (2019). https://doi.org/10.1111/jace.15936
• M. Ahmadzadeh, T.A. Olds, A. Scrimshire, P.A. Bingham, and J.S. McCloy, “Structure and properties of Na₅FeSi₄O₁₂ crystallized from 5Na₂O-Fe₂O₃-8SiO₂ glass,” Acta Crystallographica Section C, 74(12), 1595-1602 (2018). https://doi.org/10.1107/S2053229618014353
• M. Ahmadzadeh, A. Scrimshire, P.A. Bingham, and J. McCloy, “Structural Role of Iron in Nepheline-based Aluminosilicates for Nuclear Waste Applications,” Proc. Waste Management WM2018, 18192 (2018). http://www.xcdsystem.com/wmsym/2018/pdfs/FinalPaper_18192_0122022557.pdf
• José Marcial, Joey Kabel, Muad Saleh, Yaqoot Shaharyar, Ashutosh Goel, John McCloy, “Structural dependence of crystallization in glasses along the nepheline (NaAlSiO₄)-eucryptite (LiAlSiO₄) join,” Journal of the American Ceramic Society, 101(7), 2840-2855 (2018). http://dx.doi.org/doi/10.1111/jace.15439
• Ambar Deshkar, José Marcial, Scott A. Southern, Libor Kobera, David L. Bryce, John S. McCloy, Ashutosh Goel, “Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO₄) based alkali/alkaline-earth aluminosilicate glasses,” Journal of American Ceramic Society, 100(7), 2859-2878 (2017). http://dx.doi.org/10.1111/jace.14845
• Mostafa Ahmadzadeh, José Marcial, John McCloy, “Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO₄-NaFeSiO₄ join,” Journal of Geophysical Research: Solid Earth, 122(4), 2504-2524 (2017).http://dx.doi.org/10.1002/2016JB013661
• J. McCloy and A. Goel, “Glass-ceramics for nuclear-waste immobilization,” MRS Bulletin, 42(3), 233-240 (2017). (2017). http://dx.doi.org/10.1557/mrs.2017.8
• J. Marcial, M. Ahmadzadeh, J.S. McCloy, “Effect of Li, Fe, and B Addition on the Crystallization Behavior of Sodium Aluminosilicate Glasses as Analogues for Hanford High Level Waste Glasses,” MRS Advances 2(10), 549-555 (2016).  http://dx.doi.org/10.1557/adv.2016.628
• Y. Shaharyar, J. Cheng, E. Han, A. Maron, J. Weaver, J. Marcial, J. McCloy, A. Goel, “Elucidating the effect of iron speciation (Fe²⁺/Fe³⁺) on crystallization kinetics of sodium aluminosilicate glasses,” Journal of the American Ceramic Society, 99(7), 2306-2315 (2016). http://dx.doi.org/10.1111/jace.14239.
• J. Marcial, J. Crum, O. K. Neill, J. S. McCloy, “Nepheline Structural and Chemical Dependence on Melt Composition,” American Mineralogist, 101, 266-276 (2016). http://dx.doi.org/10.2138/am-2016-5370.
• J. Marcial, J. Kabel, M. Saleh, Y. Shaharyar, A. Goel, J. McCloy, “Effect of B on Crystallization of Li and Na aluminosilicates,” Proc. Waste Management WM2016, 16323 (2016).  http://www.wmsym.org/archives/2016/pdfs/16323.pdf
• J. Marcial, J. McCloy, O. Neill, “Nepheline Crystallization in High-Alumina High-Level Waste Glass,” Proc. Materials Research Society (MRS) Vol 1744, pp 85–91, Dec 1-5, 2014, Boston, MA (2015). http://dx.doi.org/10.1557/opl.2015.382
• J. Weaver, N. Wall, J. McCloy, “Wet Chemical and UV-Vis Spectrometric Iron Speciation in Low and Intermediate Level Nuclear Waste Glasses,” Proc. Materials Research Society (MRS) Vol 1744, pp 93-100, Dec 1-5, 2014, Boston, MA (2015).http://dx.doi.org/10.1557/opl.2015.481